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锍镍试金富集-等离子体质谱法测定西太平洋富钴结壳中的铂族元素
引用本文:石贵勇,孙晓明,屈文俊,薛婷,张美,熊德信,王生伟.锍镍试金富集-等离子体质谱法测定西太平洋富钴结壳中的铂族元素[J].岩矿测试,2007,26(2):113-116.
作者姓名:石贵勇  孙晓明  屈文俊  薛婷  张美  熊德信  王生伟
作者单位:1. 中山大学地球科学系,广东,广州,510275
2. 国家地质实验测试中心,北京,100037
基金项目:国家自然科学基金;国际海底区域研究开发课题资助项目;中国科学院重点实验室基金;高等学校博士学科点专项科研项目
摘    要:根据西太平洋麦哲伦海山富钴板状结壳样品的成分特征,对常规的锍镍试金配方作了改进;酌情减少捕集剂羰基镍的加入量,可显著降低铂族元素的空白值。富集后的样品,采用电感耦合等离子体质谱测定铂族元素(PGE)。其中,Ru、Rh、Pd、Ir和Pt用常规外标法测定,^175Lu作内标;Os用同位素稀释法测定。用国家一级标准物质GBW07290和GBW07291作监控分析质量的参考样,结果满足要求。

关 键 词:富钴结壳  铂族元素  锍镍试金  电感耦合等离子体质谱法
文章编号:0254-5357(2007)02-0113-04
收稿时间:2006/5/17 0:00:00
修稿时间:2006-05-172006-09-11

Determination of Platinum Group Elements in Cobalt-rich Crusts from the West Pacific Ocean by Nickel Sulphide Fire Assay-ICPMS
SHI Gui-yong,SUN Xiao-ming,QU Wen-jun,XUE Ting,ZHANG Mei,XIONG De-xin,WANG Sheng-wei.Determination of Platinum Group Elements in Cobalt-rich Crusts from the West Pacific Ocean by Nickel Sulphide Fire Assay-ICPMS[J].Rock and Mineral Analysis,2007,26(2):113-116.
Authors:SHI Gui-yong  SUN Xiao-ming  QU Wen-jun  XUE Ting  ZHANG Mei  XIONG De-xin  WANG Sheng-wei
Affiliation:1. Department of Earth Sciences, Sun Yat-sen University, Guangzhou 510275, China; 2. National Reseach Center for Geoanalysis, Beijing 100037, China
Abstract:According to mineralogical and chemical characteristics of cobalt-rich crust samples from the west Pacific ocean,the reagent formula used in common nickel sulfide fire assay preconcentration for PGE analysis were modified.The background of the procedure for PGEs was improved remarkably by reducing the quantity of the collector of carbonyl nickel powder.Ru,Rh,Pd,Ir and Pt was determined by ICP-MS with~(175)Lu as internal standard.Os was determined by isotope dilution-ICPMS.The method has been verified by determination of PGEs in National Standard Reference samples(GBW 07290 and GBW 07291)with satisfactory results.
Keywords:cobalt-rich crust sample  platinum group element(PGE)  nickel sulphide fire assay  inductively coupled plasma mass spectrometry
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